4-Ethoxy-N-(3-phenylprop-2-enylidene)aniline
نویسندگان
چکیده
The title compound, C(17)H(17)NO, was prepared by the condensation of cinnamaldehyde with p-phenetidine in ethanol. The prop-2-enyl-idene group exhibits an E configuration at the N=C and C=C double bonds, with C-N-C-C and C-C-C-C torsion angles of -179.9 (3) and -175.9 (3)°, respectively. The prop-2-enyl-idene group is not strictly planar [maximum deviation = 0.054 (4) Å] and forms dihedral angles of 28.0 (3) and 34.9 (3)° with the attached aromatic rings.
منابع مشابه
2-Hydroxy-N′-[(1E,2E)-3-phenylprop-2-enylidene]benzohydrazide
In mol-ecule of the title compound, C(16)H(14)N(2)O(2), the two aromatic rings form a dihedral angle of 6.93 (3)° and an intramolecular N-H⋯O hydrogen bond occurs. In the crystal structure, inter-molecular O-H⋯O hydrogen bonds link the mol-ecules into zigzag chains running in the [10] direction.
متن کامل[Bis(3-phenylprop-2-enylidene)propane-1,3-diamine-κ2 N,N′]dibromidocobalt(II)
In the crystal structure of the title compound, [CoBr(2)(C(21)H(22)N(2))], the Co(II) atom is four-coordinated by two bromide anions and two N atoms from the bidentate Schiff base ligand in a distorted tetra-hedral geometry.
متن کاملBis[benzyl 3-(3-phenylprop-2-enylidene)dithiocarbazato-κ2 N 3,S]cadmium
In the title complex, [Cd(C(17)H(15)N(2)S(2))(2)], the Cd(II) ion is located on a twofold rotation axis and exhibits a coordination number of four within a very distorted coordination environment that is best described as bis-phenoidal. The two deprotonated Schiff base ligands chelate the Cd(II) ion through the azomethine N and the thiol-ate S atom. The dihedral angle between the two chelating ...
متن کاملMethyl 3-[(E,E)-3-phenylprop-2-enylidene]dithiocarbazate
In the title compound, C(11)H(12)N(2)S(2), the dithio-carbazate group adopts an EE configuration with respect to the C=C and C=N bonds of the propenyl-idene group. The atoms of the propenyl-idene and dithio-carbazate unit are essentially co-planar, with a maximum deviation of 0.058 (1) Å; the phenyl ring forms a dihedral angle of 18.3 (1)° with this fragment. In the crystal, mol-ecules form inv...
متن کاملBis[benzyl N′-(3-phenylprop-2-enylidene)hydrazinecarbodithioato-κ2 N′,S]zinc(II)
In the title Zn(II) complex, [Zn(C(17)H(15)N(2)S(2))(2)], the Zn(II) atom lies on a twofold rotation axis. It exists in a tetra-hedral geometry, chelated by two deprotonated Schiff base ligands. The dihedral angle between each ligand is 71.48 (8)°. Mol-ecules are connected by weak C-H⋯S inter-molecular inter-actions into chains along the c axis. The crystal structure is further stabilized by C-...
متن کامل